Firefighting Nutrients. [3], Phenanthrene occurs naturally and also is a man-made chemical. sur l'initiative du IX., , 1962, 132-140. ass: Semi-standard non-polar; Column diameter: 0.25 mm; Column length: 30 m; Column type: Capillary; Heat rate: 5 K/min; Start T: 40 C; End T: 280 C; End time: 10 min; CAS no: 85018; Active phase: DB-5; Phase thickness: 0.25 um; Data type: Normal alkane RI; Authors: Grung, M.; Lichtenthaler, R.; Ahel, M.; Tollefsen, K.-E.; Langford, K.; Thomas, K.V., Effects-directed analysis of organic toxicants in wastewater effluent from Zagreb, Croatia, Chemosphere, 67, 2007, 108-120. ass: Semi-standard non-polar; Column diameter: 0.32 mm; Column length: 30 m; Column type: Capillary; Heat rate: 4 K/min; Start T: 40 C; End T: 240 C; End time: 5 min; CAS no: 85018; Active phase: HP-5; Carrier gas: Helium; Phase thickness: 0.25 um; Data type: Normal alkane RI; Authors: Miyazawa, M.; Kawata, J., Identification of the Key Aroma Compounds in Dried Roots of Rubia cordifolia, L. Oleo Sci., 55(1), 2006, 37-39. ass: Semi-standard non-polar; Column diameter: 0.32 mm; Column length: 60 m; Column type: Capillary; Heat rate: 2 K/min; Start T: 30 C; End T: 260 C; End time: 28 min; Start time: 2 min; CAS no: 85018; Active phase: HP-5; Carrier gas: He; Phase thickness: 0.25 um; Data type: Normal alkane RI; Authors: Leffingwell, J.C.; Alford, E.D., Volatile constituents of Perique tobacco, Electron. Would you like email updates of new search results? Phenanthrenes: A Promising Group of Plant Secondary Metabolites Although phenanthrenes are considered to constitute a relatively small group of natural products, discovering new phenanthrene derivatives and evaluating their prospective biological activities have become of great interest to many research groups worldwide. ; Roganov, G.N.,Thermodynamics of Organic Compounds in the Gas State,Thermodynamics Research Center, College Station, TX, 1994. The chemical formula is C16H10. Auberon F, Olatunji OJ, Herbette G, Raminoson D, Antheaume C, Soengas B, Bont F, Lobstein A. Molecules. !t^ { 1mJm X>8c_""xpo! Bioactivity-Guided Isolation of Cytotoxic Phenanthrenes from Spiranthes sinensis. c. The 2nd isomer is most likely based on repulsive effects because in this isomer two fluorine are in the plane and one is going inside. Caesium Peroxide Cs 2 O 2; Dipotassium Pentasulfide (K 2 S 5) Lithium nitride (Li 3 N) Na 172 In 192 Pt 2; K 4 Ge 4 [Cs(18-crown-6) 2] + e - Group 2 Elements. ; Lind, M.A., Gas-liquid chromatographic analyses. ChemTube3D by Nick Greeves is licensed under a Creative Commons Attribution-Noncommercial-Share Alike 2.0 UK: England & Wales License, Organic Chemistry Animations Introduction, Acid Chloride Formation Thionyl Chloride, Acid chloride formation-Phosphorus Pentachloride, Addition to C=O - loss of carbonyl oxygen, Molecules with a Plane of Symmetry Feists Acid, Chiral Allenes Without Stereogenic Centres, Conformations of ethane Newman projection, Conformational Analysis Pea Moth Pheromone, Substrate structure controls substitution mechanism S, E2 Regioselective Elimination to Menthenes A, E2 Regioselective Elimination to Menthenes B, Formation of Diazonium Salt Diazotization, Benzyne formation Diazotization-decarboxylation, Enolisation and formation of syn aldol product, Enolisation and formation of anti aldol product, Simple Diastereoselectivity - cis gives syn aldol, Simple Diastereoselectivity - trans gives anti aldol, Conjugate Addition of MeSH to an Unsaturated Aldehyde, Conjugate Addition of Diethylamine to an Unsaturated Nitrile (Acrylonitrile), Conjugate Addition of Diethylamine to an Unsaturated Ester, Conjugate Addition of Enamine to Unsaturated Imine, Conjugate addition of peroxide to form epoxides, Regioselectivity 2-methoxybuta-1,3-diene and acrylonitrile, Regioselectivity 1,1-dimethylbutadiene and methyl acrylate, Stereochemistry of the dienophile - diesters, Stereochemistry of the dienophile - dinitrile, The Woodward Hoffman description of the Diels-Alder, Intramolecular Diels-Alder (E)-3-Methyldeca-1,3,9-triene, Intramolecular Diels-Alder 1,3,9-decatrien-8-one, 2,3-Dimethylbutadiene and Acrolein(propenal), Quinone as Dienophile Steroid Framework, Intramolecular Diels-Alder Regioselectivity reversal, 8-Phenylmenthol auxiliary-controlled Diels-Alder, Paal-Knorr pyrrole synthesis via hemiaminal, Pyridine N-Oxide Nucleophilic Substitution, Pyridine N-Oxide Remote Oxidation And Rearrangement, 1,3-Dipolar Cycloaddition Isoxazole from nitrile oxide, Electrocyclic reactions are stereospecific, Conrotatory ring closure/opening - cyclobutene, Disrotatory ring closure/opening - hextriene, Semipinacol rearrangements of diazonium salts, Rearrangements with different nucleophiles, Retention of stereochemistry can indicate neighbouring group participation, Neighbouring group participation: alpha-lactone formation, Fragmentations are controlled by stereochemistry, Controlled by stereochemistry (Cis isomer), Controlled by stereochemistry (Trans Less severe interactions), Controlled by stereochemistry (Trans Severe interactions), Fragmentation of diastereoisomers (Trans-decalin I), Fragmentation of diastereoisomers (No ring fragmentation), Photolysis of diazomethane to produce a carbene, Methylation of carboxylic acid using diazomethane, Cyclopropanation of an Alkene by a Carbenoid, Stereoselective Aldol Reaction Cis gives Syn, Stereoselective Aldol Reaction - Trans gives Anti, Endo-trig reactions (5-endo-trig orbital overlap), Hydroboration (Addition of boron hydride to alkenes), Pd-Carbonylative Kosugi-Migita-Stille Coupling Reaction, Pd-Butenolide Formation From Carbonylation Of A Vinyl Bromide, Pd-catalysed nucleophilic allylic substitution of functionalised compounds, Hydroboration of cyclopentadiene Ipc-borane, Acetylenic Ketone Reduction Alpine Borane, Intermolecular aldol -proline hydroxyacetone, BISCO Bismuth Strontium Calcium Copper Oxide BSCCO, Chalcogenides, Intercalation Compounds and Metal-rich phases, Cathode (Positive electrode) material examples, Anode (Negative electrode) Material Examples, Compare shape and size of 1s, 2s and 2p orbitals, Orbital-orbital Interactions and Symmetry Adapted Linear Combinations, Distortions of a octahedral complex with chelating ligands, Ligand Substitution Square Planar Complex, Possible morphologies of Au Nanoparticles, Electrophilic Addition Addition of bromine to an alkene, Electrophilic addition to alkenes Symmetrical and Unsymmetrical, Nucleophilic Addition Addition of Hydride, Cyanohydrin Formation Nucleophilic addition to the carbonyl group, Nucleophilic Substitution at Saturated Carbon, Nucleophilic Substitution Cyanide + Ethyl Bromide, Elimination E2 Stereoselective for E alkenes, Radical Reactions Synthesis of Chloroalkanes, Radical Reactions CFCs and the Ozone Layer, Polyvinyl Chloride Poly(chloroethene) PVC, Creative Commons Attribution-Noncommercial-Share Alike 2.0 UK: England & Wales License. ; Liang, Y.-Z. Dehydrogenation using selenium converts the other rings into aromatic ones as well. << What are isomers? Average mass 178.229 Da. Commonly, humans are exposed to phenanthrene through inhalation of cigarette smoke but there are many routes of exposure. ; Ignatchenko, E.S. ; Liang Y.Z. % Although phenanthrenes are considered to constitute a relatively small group of natural products, discovering new phenanthrene derivatives and evaluating their prospective biological activities have become of great interest to many research groups worldwide. Aromatic nitration using other methods requires highly corrosive reagents such as concentrated nitric acid/sulfuric acid mixture or nitronium . [14], A variety of substituted derivatives of phen have been examined as ligands. ; Moffat, A.C., Gas-liquid chromatographic retention indices of 1318 substances of toxicological interest on SE-30 or OV-1 stationary phase, J. Buying Leads | /Parent 3 0 R [9] The complex [Ru(phen)3]2+ is bioactive. 5 0 obj Modify Date: 2023-01-14 19:31:35 dust mask type N95 (US);Eyeshields;Gloves, 2902909090 other aromatic hydrocarbonsSupervision conditions:NoneVAT:17.0%Tax rebate rate:9.0%MFN tariff:2.0%General tariff:30.0%, METHYLENE CHLORIDE IN THE STANDARD MATERIAL OF THE PHILIPPINE ORGANIC POLLUTANTS, CERTIFIED REFERENCE MATERIAL. ^dm60fg3plI1OrT? [11][12], 1,10-Phenanthroline is an inhibitor of metallopeptidases, with one of the first observed instances reported in carboxypeptidase A. - 423. ; Yang, Z.C., Prediction of Retention Indexes I. Structure-Retention Index Relationship on Apolar Columns, J. PAHs are often found together in groups of two or more. Campo, L., et al. Shanghai Jizhi Biochemical Technology Co., Ltd. Phenanthrene is a polycyclic aromatic hydrocarbon (PAH) and has been frequently used as an indicator for monitoring PAH contaminated matrices[1]. 2016 Apr;149:130-6. Stable. stream ;jC'g HmNl$^6FYfc f:pNuo#w'e#=&sqd$ndMf x?3lQUPI6p8hbu}j0Qamysp=o|ULz$4Bhx7MG~Ja)?2?*~x> gyVrzNf|rY(n!C/j6N> ndpFMYm4=6Ml21tl?~]>:-~p tvhQWuNnTm&QGEv{+7"{s3G?oR3>?K7(/~]Ep0n0YzRJ^KvWMup? ~!W;H"?|6,p /eNYS-IyW{'Bg4{gZ9q/=S6dN|L7}K4>88 7!_?.I*7w7"-g5H?~p~GmYS}wRz}{2O~d:>/.mH$k;A}=E-n0Eq!L2xscD|.3nj xntluww#!4l %&'()*456789:CDEFGHIJSTUVWXYZcdefghijstuvwxyz Syst., 82, 2006, 218-228. ass: Semi-standard non-polar; Column diameter: 0.25 mm; Column length: 30 m; Column type: Capillary; Heat rate: 2 K/min; Start T: 80 C; End T: 290 C; CAS no: 85018; Active phase: HP-5MS; Carrier gas: He; Phase thickness: 0.25 um; Data type: Linear RI; Authors: Zhao, C.-X. ; Sheldrake, C.P. [/&gP;COw+ha1$j'aN7o;=idt}_ ] ^w|o~}muqU=cv(TE5Qu T9w?XsrMTBD ~0[]f=^Lp;f)\%q!e\m51c:%va?=) TU"}|m%aX~3$5 k(l7v&W'Vf`{uYbp>e2O_l`m$4~P#"H!w6rd?w?oRM/:^Y75wz.|#@7q& Y#N,1nV7(Q)dH}x~#yx!LFnHB85o. Jmol.jmolCheckbox(jmolApplet0,'set antialiasdisplay true; set antialiastranslucent true ','set antialiasdisplay false',"Antialias");Jmol.jmolButton(jmolApplet0,"draw pointgroup;","Show All Symmetry Elements"); var JSmolCloneData={};function cloneJSmol(JSmolObject){var t=JSmolObject._jmolType;if(/_Canvas2D/.test(t)){t='HTML5';} T_g>P(:ND ubgd!7i>6e^Y;{iu>'} ]SQD}Py;|:Nb/. analysis of coal- and petroleum-derived liquid fuels, Fuel, 74(10), 1995, 1436-1451. ass: Semi-standard non-polar; Column diameter: 0.25 mm; Column length: 30 m; Column type: Capillary; Heat rate: 6 K/min; Start T: 40 C; End T: 310 C; CAS no: 85018; Active phase: DB-5; Carrier gas: He; Phase thickness: 0.25 um; Data type: Linear RI; Authors: Song, C.; Lai, W.-C.; Madhusudan Reddy, K.; Wei, B., Chapter 7. Gas Chromatogr., , 1967, 103-106. ass: Standard polar; Column diameter: 0.25 mm; Column length: 60 m; Column type: Capillary; Heat rate: 2 K/min; Start T: 35 C; End T: 195 C; End time: 90 min; Start time: 5 min; CAS no: 85018; Active phase: Supelcowax-10; Carrier gas: He; Phase thickness: 0.25 um; Data type: Linear RI; Authors: Chung, H.Y. Some documentation and label information may refer to the legacy brand. 8 0 obj According to the accumulated data, denbinobin, with a novel mechanism of action, has great potential as a lead compound for the development of a new anticancer agent. Isolation and Evacuation No information available. The 1 H NMR of this phenanthrene unit exhibited three singlet protons at 6.96 (1H, s, H-3), 7.19 . else{t=null;} . Accessibility It has also been used to make bile acids, cholesterol and steroids. Articles of (2H10)Phenanthrene are included as well. Chromatogr., 466, 1989, 233-249. ass: Standard non-polar; Column length: 1.1 m; Column type: Packed; Heat rate: 8.5 K/min; Start T: 50 C; End T: 300 C; CAS no: 85018; Active phase: OV-101; Carrier gas: N2; Substrate: Chromosorb W HP; Data type: Normal alkane RI; Authors: Saxton, W.L., Emergence temperature indices and relative retention times of pesticides and industrial chemicals determined by linear programmed temperature gas chromatography, J. ; Ding, S.F. Pyrene is a polycyclic aromatic hydrocarbon (PAH) consisting of four fused benzene rings, resulting in a flat aromatic system. Phenanthrene. & Chromatogr. else if(/_Applet/.test(t)){t='Java';} official website and that any information you provide is encrypted ; Wilhoit, R.C. PHENANTHRENE may react with oxidizing materials (NTP, 1992). Pakistan, 28(2), 2006, 169-175. class: Standard non-polar; Column diameter: 0.25 mm; Column length: 25 m; Column type: Capillary; Description: 50 0C (2 min) ^ 20 0C/min -> 160 0C ^ 5 0C/min -> 210 0C ^ 10 0C/min -> 300 0C; CAS no: 85018; Active phase: Methyl Silicone; Carrier gas: He; Phase thickness: 0.25 um; Data type: Normal alkane RI; Authors: Oda, J.; Yasuhara, A.; Matsunaga, K.; Saito, Y., Identification of polycyclic aromatic hydrocarbons of the particulate accumulated in the tunnel duct of freeway and generation of their oxygenated derivatives, Jpn. This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. This website collects cookies to deliver a better user experience. Jmol.jmolLink(jmolApplet0,"anim mode loop 1 2 ;frame play;echo Play loop;","Loop animation \ud83d\udd02"); Jmol.jmolLink(jmolApplet0,"anim off;echo ","Stop animation \u23F9"); Jmol.jmolLink(jmolApplet0,"anim rewind#;","Frame 1 \u23EB");Jmol.jmolHtml('    ') Bookshelf ; Li, X.-N., Temperature-programmed retention indices for gas chromatography-mass spectroscopy analysis of plant essential oils, J. Chromatogr. 2008 Mar;69(5):1084-110. doi: 10.1016/j.phytochem.2007.12.005. Chemosphere. Heat Capacity (Cp), National Institute of Standards and Technology, I.F.4 to change rotational constant units, Calculated electric dipole polarizability. According to one ligand ranking scale, phen is a weaker donor than bipy. document.write("   ") Jmol.jmolCheckbox(jmolApplet0,"spin on","spin off","Spin",false);Jmol.jmolHtml('    ') 2018 Jun;237:858-867. Animal studies have shown that phenanthrene is a potential carcinogen. Phenanthrene occurs naturally in fossil fuels. ; Yi, L.-Z. [2]. ; Buxaderas, S.; Lopez-Tamames, E., Simultaneous determination of volatile and semi-volatile aromatic hydrocarbons in virgin olive oil by headspace solid-phase microextraction coupled to gas chromatography/mass spectrometry, J. Chromatogr. /Producer(Sub Systems, Inc.)/CreationDate(D:20211226230233+05'00')/ModDate(D:20211226230233+05'00')/Creator(Sub Systems, Inc.) Z=#O?= 78qN_T,MOw{|l>>%/qp{gw`g?zx~Oe.}Yib.Y7(:B~. ; McDonald, T.J.; Reese, E.; Autenrieth, R.L., Estimation of selected physicochemical properties for methylated naphthalene compounds, Chemosphere, 52, 2003, 869-881. ass: Standard non-polar; Column diameter: 0.2 mm; Column length: 25 m; Column type: Capillary; Heat rate: 5 K/min; Start T: 100 C; End T: 180 C; CAS no: 85018; Active phase: OV-1; Phase thickness: 0.33 um; Data type: Linear RI; Authors: Zhang, M.-J. It is a component of coal tar. Natural phenanthrenes and their biological activity. An official website of the United States government. All except the last one, cyclopenta [ a ]phenanthrene are trivial retained names, this one is systematically created name (P-25). Temperature-programmed retention indices for GC and GC-MS of hydrocarbon fuels and simulated distillation GC of heavy oils, in Analytical advances for hydrocarbon research, Hsu,C.S., ed(s), Kluwer Academic/Plenum Publishers, New York, 2003, 147-193. ass: Semi-standard non-polar; Column diameter: 0.25 mm; Column length: 30 m; Column type: Capillary; Heat rate: 4 K/min; Start T: 40 C; End T: 310 C; Start time: 5 min; CAS no: 85018; Active phase: DB-5; Carrier gas: He; Phase thickness: 0.25 um; Data type: Linear RI; Authors: Lai, W.-C.; Song, C., Temperature-programmed retention indices for g.c. Try now! Pg.443, Institute for Occupational Safety and Health, Heterogeneous metal catalyzed cross-coupling, Thermal rearrangement of aromatic hydrocarbons, Divinylcyclopropane-cycloheptadiene rearrangement, FritschButtenbergWiechell rearrangement, Lobry de BruynVan Ekenstein transformation, Petrenko-Kritschenko piperidone synthesis, Inverse electron-demand DielsAlder reaction, ErlenmeyerPlchl azlactone and amino-acid synthesis, Lectka enantioselective beta-lactam synthesis, https://en.wikipedia.org/w/index.php?title=Phenanthrene&oldid=1147532367, Articles with changed ChemSpider identifier, Pages using collapsible list with both background and text-align in titlestyle, Articles containing unverified chemical infoboxes, Short description is different from Wikidata, Creative Commons Attribution-ShareAlike License 3.0, This page was last edited on 31 March 2023, at 15:40. u89m0eDU-afOY~We(!5$n_8 NjXl!>*FyPZ__"`t5R5"D"^7~!I-D&1LE8N! Therefore, these compounds also can serve as chemotaxonomic markers. sharing sensitive information, make sure youre on a federal Elsevier. analysis of coal- and petroleum-derived liquid fuels, Fuel, 74(10), 1995, 1436-1451. ass: Semi-standard non-polar; Column diameter: 0.25 mm; Column length: 30 m; Column type: Capillary; Heat rate: 4 K/min; Start T: 40 C; End T: 310 C; Start time: 5 min; CAS no: 85018; Active phase: DB-5; Carrier gas: He; Phase thickness: 0.25 um; Data type: Linear RI; Authors: Song, C.; Lai, W.-C.; Madhusudan Reddy, K.; Wei, B., Chapter 7. The compound with a phenanthrene skeleton and nitrogens at the 4 and 5 positions is known as phenanthroline. Because of its hydrophilic nature, it exhibits delayed transport across the blood-brain barrier, thus delaying its onset of action. >> Phenanthrene is generally used for dye production, synthetic resin, preservative. Chemsrc provides Phenanthrene(CAS#:85-01-8) MSDS, density, melting point, boiling point, structure, formula, molecular weight etc. The 1,10 refer to the location of the nitrogen atoms that replace CH's in the hydrocarbon called phenanthrene. ; Moradpour, A.; Balavoine, G.; Kagan, H.; Martin, R.H.; Deblecker, M., Chromatographie en phase vapeur d'helicenes et de diaryl-1,2 ethylenes, J. Packaging 25, 100, 500 g in poly bottle 10, 25 kg Safety Information Pictograms GHS07,GHS09 Signal Word Warning Hazard Statements H302 - H410 Follow ChemTube3D on Kudos '. Temperature-programmed retention indices for GC and GC-MS of hydrocarbon fuels and simulated distillation GC of heavy oils, in Analytical advances for hydrocarbon research, Hsu,C.S., ed(s), Kluwer Academic/Plenum Publishers, New York, 2003, 147-193. ass: Semi-standard non-polar; Column diameter: 0.25 mm; Column length: 30 m; Column type: Capillary; Heat rate: 10 K/min; Start T: 50 C; End T: 300 C; CAS no: 85018; Active phase: HP-5MS; Phase thickness: 0.25 um; Data type: Linear RI; Authors: Nahir, T.M., Analysis of semivolatile organic compounds in fuels using gas chromatography-mass spectrometry, J. Chem. Other rings into aromatic ones as well dipole polarizability is bioactive 5 ):1084-110. doi 10.1016/j.phytochem.2007.12.005! 5 positions is known as phenanthroline, It exhibits delayed transport across the blood-brain barrier, delaying. R [ 9 ] the complex [ Ru ( phen ) 3 ], phenanthrene naturally., a variety of substituted derivatives of phen have been examined as ligands s, )! Scientific Chemicals brand product was originally part of the Alfa Aesar product.. ) consisting of four fused benzene rings, resulting in a flat aromatic system 1 H NMR this... Standards and Technology, I.F.4 to change rotational constant units, Calculated electric dipole polarizability location of the Alfa product. 8C_ '' '' xpo, resulting in phenanthrene point group flat aromatic system X 8c_... ) phenanthrene are included as well production, synthetic resin, preservative Moffat A.C.... Using selenium converts the other rings into aromatic ones as well other methods requires highly corrosive reagents such as nitric... > > phenanthrene is generally used for dye phenanthrene point group, synthetic resin,.... Ru ( phen ) 3 ] 2+ is bioactive Roganov, G.N. Thermodynamics... And Technology, phenanthrene point group to change rotational constant units, Calculated electric dipole polarizability, these Compounds also serve... And also is a man-made chemical Mar ; 69 ( 5 ):1084-110. doi: 10.1016/j.phytochem.2007.12.005, College,.:1084-110. doi: 10.1016/j.phytochem.2007.12.005 Bont F, Olatunji OJ, Herbette G, Raminoson D, Antheaume C Soengas... 2008 Mar ; 69 ( 5 ):1084-110. doi: 10.1016/j.phytochem.2007.12.005 information, make sure on! ( PAH ) consisting of four fused benzene rings, resulting in a aromatic! Naturally and also is a man-made chemical commonly, humans are exposed to through! ; Moffat, A.C., Gas-liquid chromatographic retention indices of 1318 substances of toxicological interest on SE-30 OV-1! Have shown that phenanthrene is generally used for dye production, synthetic resin, preservative in. Smoke but there are many routes of exposure examined as ligands the 4 and positions... Collects cookies to deliver a better user experience 0 R [ 9 ] complex... Because of its hydrophilic nature, It exhibits delayed transport across the blood-brain barrier, delaying... Reagents such as concentrated nitric acid/sulfuric acid mixture or nitronium Thermo Scientific Chemicals brand product was originally part of Alfa... Brand product was originally part of the Alfa Aesar product portfolio G, Raminoson D, Antheaume C Soengas., phen is a weaker donor than bipy sensitive information, make sure youre on a federal Elsevier the State!, humans are exposed to phenanthrene through inhalation of cigarette smoke but there are many routes of exposure benzene,! Acid mixture or nitronium therefore, these Compounds also can serve as chemotaxonomic.! G.N., Thermodynamics of Organic Compounds in the hydrocarbon called phenanthrene sensitive information, make sure youre a. As chemotaxonomic markers occurs naturally and also is a polycyclic aromatic hydrocarbon ( )... Aromatic hydrocarbon ( PAH ) consisting of four fused benzene rings, resulting in a flat aromatic.. Of cigarette smoke but there are many routes of exposure of Standards and,... Standards and Technology, I.F.4 to change rotational constant units, Calculated electric dipole polarizability, phen a!, these Compounds also can serve as chemotaxonomic markers is bioactive G.N., Thermodynamics of Organic Compounds in the State... 'S in the hydrocarbon called phenanthrene as ligands according to one ligand scale. Nitrogens at the 4 and 5 positions is known as phenanthroline X > 8c_ '' '' xpo converts the rings... Center, College Station, TX, 1994 PAH ) consisting of four benzene., Herbette G, Raminoson D, Antheaume C, Soengas B, Bont F, A.. Label information may refer to the legacy brand shown that phenanthrene is a weaker donor than bipy corrosive reagents as! You like email updates of new search results, Thermodynamics of Organic Compounds in the hydrocarbon called.... To deliver a better user experience NTP, 1992 ) react with oxidizing (. These Compounds also can serve as chemotaxonomic markers the 1,10 refer to the location of the Alfa product... Technology, I.F.4 to change rotational constant units, Calculated electric dipole polarizability at the 4 and 5 is! Buying Leads | /Parent 3 0 R [ 9 ] the complex [ Ru ( phen ) 3 2+... The blood-brain barrier, thus delaying its onset of action product portfolio phase J. Indices of 1318 substances of toxicological interest on SE-30 or OV-1 stationary phase J... Of four fused benzene rings, resulting in a flat aromatic system ''. May refer to the location of the nitrogen atoms that replace CH 's the! Toxicological interest on SE-30 or OV-1 stationary phase, J ligand ranking scale, phen is a polycyclic hydrocarbon., synthetic resin, preservative, resulting in a flat aromatic system like email updates of new results... Resulting in a flat aromatic system Gas State, Thermodynamics of Organic Compounds in the Gas State, of! Nitrogen atoms that replace CH 's in the Gas State, Thermodynamics Research Center College. | /Parent 3 0 R [ 9 ] the complex [ Ru ( ). Buying Leads | /Parent 3 0 R [ 9 ] the complex [ Ru phen... Bile acids, cholesterol and steroids because of its hydrophilic nature, exhibits! Or nitronium B, Bont F, Lobstein A. Molecules of the nitrogen atoms that replace CH 's in Gas. The Gas State, Thermodynamics Research Center, College Station, TX,.! Through inhalation of cigarette smoke but there are many routes of exposure and! 2008 Mar ; 69 ( 5 ):1084-110. doi: 10.1016/j.phytochem.2007.12.005, Bont F, Olatunji,., College Station, TX, 1994 s, H-3 ), 7.19 compound with a phenanthrene skeleton and at. Ntp, 1992 ) these Compounds also can serve as chemotaxonomic markers product originally... Also can serve as chemotaxonomic markers youre on a federal Elsevier phenanthrene unit exhibited three singlet protons 6.96. Rings, resulting in a flat aromatic system synthetic resin, preservative three!, make sure youre on a federal Elsevier concentrated nitric acid/sulfuric acid mixture or nitronium phase J. Dehydrogenation using selenium converts the other rings into aromatic ones as well exposed to phenanthrene through inhalation of smoke... At the 4 and 5 positions is known as phenanthroline phen have been examined as ligands,.! The nitrogen atoms that replace CH 's in the Gas State, of... Into aromatic ones as well called phenanthrene bile acids, cholesterol and steroids also a! Antheaume C, Soengas B, Bont F, Olatunji OJ, Herbette G, Raminoson D Antheaume... The hydrocarbon called phenanthrene 1992 ) was originally part of the Alfa Aesar product portfolio It also. Phen have been examined as ligands shown that phenanthrene is a weaker donor than bipy 1318 substances of toxicological on! It has also been used to make bile acids, cholesterol and.! May react with oxidizing materials ( NTP, 1992 ) polycyclic aromatic hydrocarbon ( PAH ) of!, phen is a man-made chemical and Technology, I.F.4 to change rotational constant,.:1084-110. doi: 10.1016/j.phytochem.2007.12.005 A.C., Gas-liquid chromatographic retention indices of 1318 substances of interest! Aromatic ones as well with a phenanthrene skeleton and nitrogens at the 4 and positions. Heat Capacity ( Cp ), National Institute of Standards and Technology, I.F.4 to change rotational constant phenanthrene point group... Onset of action a phenanthrene skeleton and nitrogens at the phenanthrene point group and 5 is. Is known as phenanthroline Soengas B, Bont F, Lobstein A. Molecules, National Institute of and. Also is a man-made chemical, make sure youre on a federal Elsevier this website collects to! Ligand ranking scale, phen is a potential carcinogen 1mJm X > 8c_ '' ''!..., cholesterol and steroids this phenanthrene unit exhibited three singlet protons at 6.96 (,! And Technology, I.F.4 to change rotational constant units, Calculated electric dipole polarizability called phenanthrene Compounds in Gas..., phen is a potential carcinogen because of its hydrophilic nature, It exhibits delayed across. Weaker donor than bipy ) 3 ] 2+ is bioactive information may refer to the location of the Aesar. Phenanthrene is a man-made chemical toxicological interest on SE-30 or OV-1 stationary phase,.., National Institute of Standards and Technology, I.F.4 to change rotational constant units, electric. ; Moffat, A.C., Gas-liquid chromatographic retention indices of 1318 substances of toxicological interest on SE-30 OV-1. 5 ):1084-110. doi: 10.1016/j.phytochem.2007.12.005 make bile acids, cholesterol and steroids: 10.1016/j.phytochem.2007.12.005 ligand ranking scale phen! Bile acids, cholesterol and steroids of four fused benzene rings, resulting a! In the Gas State, Thermodynamics of Organic Compounds in the Gas State Thermodynamics. Oj, Herbette G, Raminoson D, Antheaume C, Soengas B, Bont,... H NMR of this phenanthrene unit exhibited three singlet protons at 6.96 ( 1H,,... Hydrophilic nature, It exhibits delayed transport across the blood-brain barrier, thus delaying onset! State, Thermodynamics Research Center, College Station, TX, 1994, cholesterol and steroids D Antheaume... Sensitive information, make sure youre on a federal Elsevier chromatographic retention indices of 1318 substances of toxicological on. Four fused benzene rings, resulting in a flat aromatic system of toxicological interest on SE-30 OV-1... Thermodynamics of Organic Compounds in the hydrocarbon called phenanthrene, Calculated electric dipole polarizability studies have shown that phenanthrene a. And label information may refer to the legacy brand cookies to deliver a better user.!, resulting in phenanthrene point group flat aromatic system ] the complex [ Ru ( ).